Synthesis of Colloidal Metal Chalcogenide Nanocrystals

A method of synthesizing colloidal nanocrystals is disclosed using metal oxides or metal salts as a precursor. The metal oxides or metal salts are combined with a ligand and then heated in combination with a coordinating solvent. Upon heating, the metal oxides or salts are converted to stable soluble metal complexes. The metal complexes are formed by cationic species combining with the ligands and/or with the coordinating solvent. Finally, an elemental chalcogenic precursor, for example, Se, Te, or S, is introduced into the soluble metal complex to complete the formation of the nanocrystals at a controllable rate. High-quality CdSe, CdTe, and CdS nanocrystals are produced when CdO is used as the cadmium precursor. With the present method, the size, size distribution, and shape (dots or rods) of the resulting nanocrystals can be controlled during growth. For example, the resulting nanocrystals are nearly monodisperse without any size separation. Further, the method represents a major step towards a green chemistry approach for synthesizing high-quality semiconductor nanocrystals

Trajectory-Aware Body Interaction Transformer for Multi-Person Pose Forecasting

Multi-person pose forecasting remains a challenging problem, especially in modeling fine-grained human body interaction in complex crowd scenarios. Existing methods typically represent the whole pose sequence as a temporal series, yet overlook interactive influences among people based on skeletal body parts. In this paper, we propose a novel Trajectory-Aware Body Interaction Transformer (TBIFormer) for multi-person pose forecasting via effectively modeling body part interactions. Specifically, we construct a Temporal Body Partition Module that transforms all the pose sequences into a Multi-Person Body-Part sequence to retain spatial and temporal information based on body semantics. Then, we devise a Social Body Interaction Self-Attention (SBI-MSA) module, utilizing the transformed sequence to learn body part dynamics for inter- and intra-individual interactions. Furthermore, different from prior Euclidean distance-based spatial encodings, we present a novel and efficient Trajectory-Aware Relative Position Encoding for SBI-MSA to offer discriminative spatial information and additional interactive clues. On both short- and long-term horizons, we empirically evaluate our framework on CMU-Mocap, MuPoTS-3D as well as synthesized datasets (6 ~ 10 persons), and demonstrate that our method greatly outperforms the state-of-the-art methods. Code will be made publicly available upon acceptance.Comment: Accepted by CVPR2023, 8 pages, 6 figures. arXiv admin note: text overlap with arXiv:2208.0922

Deciphering Charging Status, Absolute Quantum Efficiency, and Absorption Cross Section of MultiCarrier States in Single Colloidal Quantum Dot

Upon photo- or electrical-excitation, colloidal quantum dots (QDs) are often found in multi-carrier states due to multi-photon absorption and photo-charging of the QDs. While many of these multi-carrier states are observed in single-dot spectroscopy, their properties are not well studied due to random charging/discharging, emission intensity intermittency, and uncontrolled surface defects of single QD. Here we report in-situ deciphering the charging status, and precisely assessing the absorption cross section, and determining the absolute emission quantum yield of mono-exciton and biexciton states for neutral, positively-charged, and negatively-charged single core/shell CdSe/CdS QD. We uncover very different photon statistics of the three charge states in single QD and unambiguously identify their charge sign together with the information of their photoluminescence decay dynamics. We then show their distinct photoluminescence saturation behaviors and evaluated the absolute values of absorption cross sections and quantum efficiencies of monoexcitons and biexcitons. We demonstrate that addition of an extra hole or electron in a QD changes not only its emission properties but also varies its absorption cross section

Synthesis of colloidal metal chalcogenide nanocrystals

A method of synthesizing colloidal nanocrystals is disclosed using metal oxides or metal salts as a precursor. The metal oxides or metal salts are combined with a ligand and then heated in combination with a coordinating solvent. Upon heating, the metal oxides or salts are converted to stable soluble metal complexes. The metal complexes are formed by cationic species combining with the ligands and/or with the coordinating solvent. Finally, an elemental chalcogenic precursor, for example, Se, Te, or S, is introduced into the soluble metal complex to complete the formation of the nanocrystals at a controllable rate. High-quality CdSe, CdTe, and CdS nanocrystals are produced when CdO is used as the cadmium precursor. With the present method, the size, size distribution, and shape (dots or rods) of the resulting nanocrystals can be controlled during growth. For example, the resulting nanocrystals are nearly monodisperse without any size separation. Further, the method represents a major step towards a green chemistry approach for synthesizing high-quality semiconductor nanocrystals

Colloidal metal chalcogenide nanocrystals

A method of synthesizing colloidal nanocrystals is disclosed using metal oxides or metal salts as a precursor. The metal oxides or metal salts are combined with a ligand and then heated in combination with a coordinating solvent. Upon heating, the metal oxides or salts are converted to stable soluble metal complexes. The metal complexes are formed by cationic species combining with the ligands and/or with the coordinating solvent. Finally, an elemental chalcogenic precursor, for example, Se, Te, or S, is introduced into the soluble metal complex to complete the formation of the nanocrystals at a controllable rate. High-quality CdSe, CdTe, and CdS nanocrystals are produced when CdO is used as the cadmium precursor. With the present method, the size, size distribution, and shape (dots or rods) of the resulting nanocrystals can be controlled during growth. For example, the resulting nanocrystals are nearly monodisperse without any size separation. This method represents a major step towards a green chemistry approach for synthesizing high-quality semiconductor nanocrystals

Metal doped semiconductor nanocrystals and methods of making the same

Provide doped semiconductor nanocrystals and methods of making the same

Synthesis of stable colloidal nanocrystals using organic dendrons

A method for stabilizing colloidal suspensions of nanocrystals or nanoparticles in a solvent or solid matrix is provided by coating the nanocrystals with bulky organic molecules, specifically dendrons, is described. By coating nanocrystals with a dense organic dendron coat and further cross-linking the dendron ligands, oxidation of the nanocrystals and dissociation of the ligands are avoided. This invention allows nanocrystals to undergo rigorous purification and processing. It may regularly be applied to a variety of nanocrystals